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Identifying fluorocarbons structure

 
Identifying the fluorocarbons structure from their number
Abbreviation key CFCs, HCFCs, HFCs
 
CFCs = Chloro fluorocarbons
HCFCs = Hydro chloro fluorocarbons
HFCs = Hydro fluorocarbons
Principle for identifying pure fluorocarbons formula from its number
 
  • add 90 to the product number
  • the result is a 3-digit number XYZ where :
    • X gives the number of C atoms
    • Y gives the number of H atoms ( if Y = 0 then it is a CFC )
    • Z gives the number of F atoms
    • The number of Cl atoms is given by : (2 X) - Y - Z + 2

      => If Cl = 0 it means that the product is an HFC

    • The letter is added in order to distinguish different isomers
Principle for identifying blends of fluorocarbons
  HFC refrigerant blends (i.e. mixtures of pure refrigerants) are simply numbered after an internationally accepted nomenclature. There is no logical mean to identify them.

Blends having the same pure components but with different compositions are identified with upper cases (ex R 404A:near azeotropic refrigerant containing R 125, R 143a and R 134a) 44/52/4% by weight.

Examples
 
  • CFC 12
    12 + 90 = 102
    C = 1 H = 0 F = 2 Cl = (2 x 1) - 2 + 2 = 2

    => C Cl2 F2 or difluorodichloromethane

  • HCFC 142b ()
    142 + 90 = 232
    C = 2 H = 3 F = 2 Cl = (2 x 2) - 3 - 2 + 2 = 1

    => CH3 - C Cl F2 or 1,1,1 chlorodifluoroethane (the number indicate here on which carbon the halogen is bound.

  • HFC 134a
    134 + 90 = 224
    C = 2 H = 2 F = 4 Cl = (2 x 2) - 2 - 4 + 2 = 0

    => CH2F - CF3 or 1,1,1,2 tetrafluoroethane